ASTM D859 PDF
This method is included in NEMI for informational purposes as it is approved by EPA for regulatory use. Detailed information on this method is not currently. eropoly acid. This is reduced to silicomolybdenum blue that is determined pho- tometrically. The method is analogous to APHA SiO2 D+E, ASTM D, . Find the most up-to-date version of ASTM D at Engineering
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Check the concentration of this solution gravimetrically. For measurements made at nm, silica d589 may be read directly in milligrams SiO2 per litre from the calibration curve prepared in Your comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend.
Summary of Test Method 4. It is applicable to most waters, but some waters may require filtration and dilution to remove interferences from astmm and turbidity.
Referenced Documents purchase separately The documents listed below are referenced within the subject standard but are aztm provided as part of the standard.
In solution it can exist as silicic acid or silicate ion, depending upon pH. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
ASTM D – 16 – Standard Test Method for Silica in Water
Silicon is the most abundant element in igneous rocks and is the characteristic element of all important rocks except the d895. Dehydration is completed by ignition, and the silica is volatilized as silicon tetra? Refer to Appendix X1 for historical information. Silicon is the most abundant element in igneous rocks and is the characteristic element of all important rocks except the carbonates.
For many natural waters, a measurement of molybdate-reactive silica by this test method provides a close approximation of total silica, and, in practice, the colorimetric method is frequently substituted for other more time-consuming techniques. Discard when the color darkens or a precipitate forms. It is applicable to most waters, but some waters may require filtration and dilution to remove interferences from color and turbidity.
Standard – Standard Test Method for Silica in Water ASTM D –
Each operator made six determinations at each level, for a total of 72 determinations at each level. It is particularly applicable to treated industrial waters.
The concentration of the IRM should be within the scope of the method, as de? Shelf life of this reagent may be extended by refrigeration. It is particularly applicable to treated industrial waters. The level 2 spiking solution used for the precision and bias study is a suitable IDP solution. Complex silicate residues that do not yield to this treatment are dissolved by alkali fusion and dehydrated with Astj. The upper limit for acceptable precision and the range of acceptable recoveries are detailed below: After dissolving, add the solution to mL of a solution containing 30 g of sodium hydrogen sul?
It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Phosphate interference is eliminated by the addition of oxalic acid. The IDP wstm contains method analytes of known concentration, prepared from a different source to the calibration standards, used to fortify reagent water. Quality Control QC This can be compensated for by preparing standards in a matrix similar to that of samples or by using a standard additions technique.
For seawater or brines, this test method is applicable only if matched matrix standards or standard addition techniques are employed.
Standard Test Method for Silica in Water
Longer path length cells 40 to 50 mm are recommended for concentrations below 0. The lower limit of this method is 5 mg of silica. Historical Version s – view previous versions of standard. Measurements may be made at nm with a spectrophotometer, or to nm with a?
It may be applied to natural waters and wastewaters following filtration or dilution, or both. Due to the complexity of silica chemistry, the form of silica measured is de? This is acceptable when, as frequently occurs, the molybdate-reactive silica is in the milligram per litre concentration range while the nonmolybdate-reactive silica, if present at all, is in the microgram per litre concentration range.
Silica removal is commonly accomplished by ion exchange, distillation, reverse osmosis, or by precipitation, usually with magnesium compounds in a hot or cold lime softening process. In solution it can exist as silicic acid or silicate ion, depending upon pH.
If non-detects are expected in all the samples to be analyzed, a Matrix Spike Duplicate should be run instead. Individual reprints single or multiple copies of this standard may be obtained by contacting ASTM at the above address or 8d59 phonefaxor service astm. It may d8859 applied to natural waters and wastewaters following?
Silica may exist in suspended particles, as a colloid, or in 8d59.